Article ID Journal Published Year Pages File Type
4990272 Separation and Purification Technology 2017 32 Pages PDF
Abstract
Wine lees from red wine production are important sources for the recovery of antioxidant compounds, namely polyphenols and polysaccharides. In this work a set of ultrafiltration and nanofiltration membranes was investigated aiming the fractionation of polyphenols and polysaccharides present in wine lees. Permeation fluxes and solute rejection coefficients were evaluated in terms of transmembrane pressure variation. In all the evaluated pressure range (3-15 bar), NF membrane presented a linear increase in permeation fluxes such that the ratio between permeabilities (feed solution/water) stayed constant at 0.72. In contrast, for the UF membranes this ratio decreases by increasing the pressure and the membrane's MWCO. For membranes with MWCO of 1000 and 10,000 Da, the permeabilities' ratio is reduced from 0.34 to 0.23 and from 0.29 to 0.17, respectively, as the pressure is increased from 5 to 15 bar. Ultrafiltration has proven to be effective to separate the polysaccharides of the polyphenols, so that the polysaccharides mainly stayed in the retentate stream, while polyphenols preferentially permeated these membranes. Sequentially, considering that the NF270 membrane presented polyphenols rejections higher than 92%, the polyphenols that permeated the ultrafiltration membrane may be concentrated by nanofiltration, and therefore, it can be achieved a concentrated solution having higher antioxidant activity. Thus, the integration of different membrane separation processes emerges as an alternative for the recovery of polyphenols and polysaccharides.
Related Topics
Physical Sciences and Engineering Chemical Engineering Filtration and Separation
Authors
, , ,