Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4995997 | Thermochimica Acta | 2017 | 5 Pages |
Abstract
The constructional details and performance of a low-temperature ac calorimetric system for extremely small single crystal samples of molecule-based compounds of which sensing parts is consisting of commercially available micro-chip device of XEN-39390 are reported. We succeeded to detect the thermal anomaly related to the glass formation of the ethylene conformation in a charge transfer complex of κ-(BEDT-TTF)2Cu[N(CN)2]Br, where BEDT-TTF is bisethylenedithiotetrathiafulvalene. From the analyses of temperature and frequency dependences of heat capacity, we suggest that XEN-39390 can give similar experimental resolution as that of TCG-3880 with much smaller single crystals less than 100 ng. We also observed a glass-like freezing of molecular dynamics in the large asymmetric cations in EtMe3Sb[Pd(dmit)2]2 which are known as a spin liquid compound by single piece of crystal where dmit is 1,3-dithiole-2-thione-4,5-dithiolate. The comparison with the relaxation calorimetry result with absolute precision is performed.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Fluid Flow and Transfer Processes
Authors
Michinori Murase, Satoshi Yamashita, Ryo Yoshimoto, Shusaku Imajo, Yasuhiro Nakazawa, Kohei Ueda, Reizo Kato,