| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 50030 | Catalysis Communications | 2014 | 4 Pages |
•We have developed the ion oxide catalyzed reducion of acid chlorides to aldehyds.
Iron-catalyzed reduction of acid chlorides to the corresponding aldehydes with a hydrosilane as a reducing agent has been developed. A simple mixture of a commercially available iron oxide (FeO) and tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) as a catalyst realized the reduction of acid chlorides to the corresponding aldehydes under mild reaction conditions.
Graphical abstractIron-catalyzed reduction of acid chlorides to the corresponding aldehydes with a hydrosilane as a reducing agent has been developed. A simple mixture of a commercially available iron oxide (FeO) and tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) as a catalyst realized the reduction of acid chlorides (1) to the corresponding aldehydes (2) under mild reaction conditions.Figure optionsDownload full-size imageDownload as PowerPoint slide
