Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5006271 | Materials Science in Semiconductor Processing | 2016 | 5 Pages |
Abstract
Surface treatment of the foreign substrate is a critical factor influencing heteroepitaxial catalyst-free growth of nanowires, their crystal quality, their diameter and their areal density. To this end, catalyst-free growth of GaN nanowires on Al2O3(0001) by plasma-assisted molecular beam epitaxy was achieved using the following substrate surface treatments: (a) deposition of a SixNy layer on nitridated Al2O3 surface, and (b) deposition of Si on bare Al2O3 surface. The nanostructure of GaN nanowires and GaN/Al2O3 interfaces was explored by quantitative high-resolution transmission electron microscopy and related analytical methods. Spontaneous growth of GaN nanowires was realized on the amorphous SixNy layer, while a discontinuous crystalline zone in contact with Al2O3 was identified as partially strained AlN. Subsequently, GaN nanowires were directly grown on top of Al2O3 among stress-free Si islands. The orientation relation of these islands with the substrate was the [112](1¯1¯1)Si//[11¯00](0001)Al2O3, providing the minimum lattice misfit between the two structures. Increasing the Si deposition time a higher density of Si islands was realized, leading to non-coalesced nanowires of lower density and better structural quality. Hence, the presence of Si islands induced a mask-like effect on the nucleation of GaN nanowires that can be exploited for a controlled catalyst-free growth of nanowires.
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Authors
T. Koukoula, J. Kioseoglou, Th. Kehagias, F. Furtmayr, M. Eickhoff, H. Kirmse, Th. Karakostas, Ph. Komninou,