Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
50073 | Catalysis Communications | 2012 | 6 Pages |
Pd–Fe–Ox catalysts for low temperature CO oxidation were supported on SBA-15, CeO2 nano-particles with rich (111) facets and CeO2 nano-rod with rich (200) facets, and characterized by X-ray diffraction, low-temperature nitrogen adsorption, transmission electron microscopy and temperature-programmed reduction. The results showed that when CeO2 nano-rod was used as a support, Pd–Fe–Ox catalyst exhibits higher activity (T100 = 10 °C), resulting from the rich (200) facets of CeO2 nano-rod, which leads to a formation of large numbers of the oxygen vacancies on the surface of Pd–Fe–Ox catalysts.
Graphical abstractPd–Fe–Ox supported on CeO2-HT with rich (200) facets shows an excellent performance for CO oxidation.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Property of support affects remarkably the activity of Pd–Fe–Ox catalyst for CO + O2. ► Pd–Fe–Ox supported on CeO2 with rich (200) facets shows an excellent performance. ► CeO2 support with rich (200) facets benefits oxygen vacancies formation on Pd–Fe–Ox.