Laser transmission welding of poly(ethylene terephthalate) and biodegradable poly(ethylene terephthalate) - Based blends

•Joining of Poly(Ethylene Terephthalate) PET and its biodegradable derivatives.•Granules of PET and biodegradable PETs modified by organic additives by extrusion compounding.•Laser Transmission Welding (LTW) with a continuous wave High Power Diode Laser (cw-HPDL).•A novel predicting analytical model derived from the mixture rule was developed.•Identification of the routes to thermal degradation of PET and biodegradable PET blends.

Joining of Poly(Ethylene Terephthalate) PET and its biodegradable derivatives is of high relevance to ensure good productive rate, low cost and operational safety for fabrication of medical and electronic devices, sport equipments as well as for manufacturing of food and drug packaging solutions. In the present investigation, granules of PET and PETs modified by organic additives, which promote biodegradation of the polymeric chains, were prepared by extrusion compounding. The achieved granules were subsequently re-extruded to shape thin (330 μm) flat sheets. Substrates cut from these sheets were joined by Laser Transmission Welding (LTW) with a continuous wave High Power Diode Laser (cw-HPDL). First, based on a qualitative evaluation of the welded joints, the most suitable operational windows for PETs laser joining were identified. Second, characterization of the mechanical properties of the welded joints was performed by tensile tests. Accordingly, Young's modulus of PET and biodegradable PET blends was studied by Takayanagi's model and, based on the experimental results, a novel predicting analytical model derived from the mixture rule was developed. Lastly, material degradation of the polymeric joints was evaluated by FT-IR analysis, thus allowing to identify the main routes to thermal degradation of PET and, especially, of biodegradable PET blends during laser processing.