Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
50111 | Catalysis Communications | 2016 | 4 Pages |
•Redisperse the Mo oxides by weakening the MoO3-Al2O3 interaction.•Transform MoO42 − or β-CoMoO4 into polymolybdate species.•Promote bulk MoO3 to form well-dispersed MoO3 species.•Remove the CoAl2O4-like species to form more Co-Mo-S active sites.•The sulfidation and morphology of active species were significantly improved.
Calcined CoMo/γ-Al2O3 catalysts were modified by citric acid (CA) with different CA/Co ratios and the corresponding structure evolutions were systematically characterized. Then combined with HDS activity results, potential redispersion effects of CA were suggested: (i) weaken the MoO3-Al2O3 interaction via competitive interacting with the OH groups of alumina surface to realize the redispersion of Mo oxides; (ii) transform tetrahedral MoO42 − or β-CoMoO4 into octahedral polymolybdate species and promote bulk MoO3 to form well-dispersed MoO3; (iii) remove the CoAl2O4-like species. These effects probably together promote the resulting sulfided catalysts with more type II CoMoS active sites, thus enhancing the HDS activity.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide