Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5012387 | Energy Conversion and Management | 2017 | 9 Pages |
Abstract
Mesoporous oil palm ash zeolite (OPAZ) was synthesized and impregnated with various lithium ion loadings (5-15Â wt%). The synthesized Li-OPAZ catalyst was used to upgrade biodiesel byproduct glycerol to glycerol carbonate (GC) via transesterification pathway. Results indicated that Li-OPAZ sustained the transesterification reaction to appreciably high glycerol conversion (100%) and GC yield (98.1%) under the optimal reaction conditions of 343Â K, 90Â min, DMC/glycerol molar ratio of 2, and 2Â wt% catalyst loading. The crystallinity and framework of zeolite was preserved after lithium incorporation with a slight decrease in pore volume and surface area. However, basicity increased with increased lithium impregnation, explaining the observed high catalytic activity of the theoretical 10Â wt% Li loaded OPAZ. Hence, 10Â wt% Li-OPAZ was reused in five successive cycles of experiment with sustained appreciable catalytic activity toward glycerol conversion and GC yield.
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Energy (General)
Authors
W.A. Khanday, P.U. Okoye, B.H. Hameed,