Fragmentation of an advanced ceramic under ballistic impact: Mechanisms and microstructure

In this paper, the impact-induced fragmentation of a commercially available hot-pressed boron carbide is explored. Fragmentation has been noted previously by many authors to be important in the impact performance of advanced ceramics, and so this paper seeks to provide some of the first near-complete and detailed measurements of individual fragment size and shape distributions available in the literature. Fragment size and shapes are quantified using methods developed in previous papers by the authors, and results reveal that two distinct fragmentation mechanisms exist as a consequence of the impact failure of boron carbide: one mechanism that creates small fragments that is associated with the coalescence of fractures originating from carbonaceous defects in the material, and one that creates larger fragments that is associated with structural failure (e.g., radial and circumferential cracking). While these mechanisms are similar to those noted for uniaxial compressive failure, results presented here highlight the importance of fragment shape as a consequence of impact failure. Namely, results indicate that both blocky and shard fragments are formed during impact into a boron carbide plate. Blocky and shard fragment types span across both the small and large fragmentation mechanisms. Using Scanning Electron Microscopy, blocky fragments were found to be associated with the predominant growth of cracks parallel to the impact direction, while shard fragments contain fracture surfaces that are associated with crack growth and coalescence in a direction perpendicular to the impact direction. The shards are, thus, believed to be a consequence of structural bending. No amorphous features were found on any blocky or shard fragments observed in this study (determined using Raman Spectroscopy), suggesting brittle fracture may be the dominant mechanisms that creates the shard fragments. Altogether, the implications of these results is that one can control fragment size and shape by controlling the carbonaceous defects population in boron carbide. This should help in the design of next-generation advanced ceramics for personal protection.