Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5021259 | Composites Part B: Engineering | 2017 | 40 Pages |
Abstract
Poly (propylene carbonate) (PPC) foams have attracted more attention in recent years because of their biodegradability and the fixation of carbon dioxide (CO2). Despite their many attractive features, a relatively low decomposition temperature, a low glass transition temperature (Tg), weak mechanical properties and poor melt strength of PPC matrix limited their commercial applications as a viable candidate for conventional plastics. In this study, we report a facile, effective, low-cost and eco-friendly approach for the preparation of PPC/PBS/PTFE ternary in situ nano-fibrillar biocomposites to significantly improve the strength and foaming ability of PPC without sacrificing their excellent biodegradability. The in situ nano-fibrillar networks in the PPC/PBS matrix demonstrated that significant reinforcement effects on the matrix strength, dynamic mechanical and rheological properties at low PTFE contents. In contrast to pure PPC, Tg increased by 15 °C, 851% higher in storage modulus and 17 times enhancement in the initial viscosity of biocomposites. In continues extrusion foaming process, the PBS domains and PTFE nano-fibrils network generated remarkable synergistic effects on the foaming behavior, resulted in higher cell densities (two orders of magnitude), compressive modulus (30 times) and compressive strength (20 times) of PPC/PBS/PTFE (70/30/3) biocomposites.
Related Topics
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Authors
Tairong Kuang, Kaican Li, Binyi Chen, Xiangfang Peng,