Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5022154 | Composites Science and Technology | 2017 | 8 Pages |
Abstract
Polymer/clay nanocomposites exhibit desirable performance and multifunctional properties. The ideal dispersion and exfoliation of clay layers in polymeric matrixes is a significant drawback that affects its application. In this study, a novel extruder generating a continuous elongation flow was used to fabricate the representative polypropylene (PP)/organic montmorillonite (OMMT) nanocomposites and then compare with the twin-screw extruder (TSE). Phase morphology, dynamic rheological properties, and mechanical properties were characterized by thermal gravimetric analysis, wide-angle X-ray diffraction, transmission electron microscopy, rotational rheometer and impact tests. The morphology and rheological behavior of the nanocomposites evidenced that ideal intercalation or/and exfoliation dispersion of OMMT in PP matrixes can be achieved under continuous elongation flow. Thus, the double-side exfoliation of the OMMT platelets combined with the pulling/diffusion process under an elongation flow is leading to an effective strengthening and toughening of PP better than that in the TSE.
Related Topics
Physical Sciences and Engineering
Engineering
Engineering (General)
Authors
Guizhen Zhang, Ting Wu, Wangyang Lin, Yongbin Tan, Rongyuan Chen, Zhaoxia Huang, Xiaochun Yin, Jinping Qu,