Article ID Journal Published Year Pages File Type
50231 Catalysis Communications 2011 5 Pages PDF
Abstract

Cu-doped titania photocatalyst supported on silica beads (Cu-TiO2/SiO2) were prepared under different Cu-ion concentration and under different calcination atmosphere. The properties and performance of Cu-TiO2/SiO2 were compared with undoped TiO2/SiO2 photocatalyst. The effect of Cu-doping and calcination atmosphere on photocatalytic degradation of phenol under both black light and visible light irradiation were investigated, where in both cases the degradation rate of phenol by Cu-doped catalyst prepared under reducing calcination atmosphere was found to be higher than the undoped catalyst or Cu-doped catalyst prepared under air atmosphere. This may be attributed to increase in visible light absorption and lengthening of photogenerated electron–hole pair recombination time. The photocatalytic beads were characterized by X-ray diffraction (XRD), UV-Vis absorption spectroscopy and SEM/EDAX analysis.

► In this research work we have modified the titania photocatalyst immobilized on silica beads by copper doping under different reducing calcination atmosphere. ► The effect of copper doping and reducing calcination atmosphere has been studied by phenol degradation under both UV and visible light irradiation. ► A new and cheaper reducing atmosphere using graphite powder has been used which has been found to be most effective. ► Since this research work is related modification of photocatalyst we think it will be better if we can publish this on your Journal.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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