Article ID Journal Published Year Pages File Type
50278 Catalysis Communications 2015 4 Pages PDF
Abstract

•Structural study of a novel binuclear Mn(II) complex•Evaluation of catalyst in Mukaiyama epoxidation reaction•Eliciting the higher efficiency in aerobic epoxidation of cyclic olefins

A novel binuclear Mn(II) complex based on a para-nitro substituted amidic ligand (N-(4-nitrophenyl)picolinamide) has been synthesized and characterized by X-ray crystallography. This complex shows a high degree of conversion and epoxide selectivity in Mukaiyama aerobic epoxidation reactions of cyclic olefins in mild conditions.

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Physical Sciences and Engineering Chemical Engineering Catalysis
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