Article ID Journal Published Year Pages File Type
50390 Catalysis Communications 2011 4 Pages PDF
Abstract

In contrast to Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate), the crystal structure of Cu3(BTC)2, a commercial metal organic framework widely used as solid catalyst, collapses when contacted with thiols under mild reaction conditions forming copper nanoparticles.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► The instability of Cu3(BTC)2 towards thiols. ► Copper nanoparticles are formed from Cu3(BTC)2. ► Characterization of copper nanoparticles by TEM and combined spectroscopic techniques.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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