Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
50390 | Catalysis Communications | 2011 | 4 Pages |
Abstract
In contrast to Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate), the crystal structure of Cu3(BTC)2, a commercial metal organic framework widely used as solid catalyst, collapses when contacted with thiols under mild reaction conditions forming copper nanoparticles.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► The instability of Cu3(BTC)2 towards thiols. ► Copper nanoparticles are formed from Cu3(BTC)2. ► Characterization of copper nanoparticles by TEM and combined spectroscopic techniques.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Amarajothi Dhakshinamoorthy, Mercedes Alvaro, Patricia Concepcion, Hermenegildo Garcia,