| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 50612 | Catalysis Communications | 2012 | 4 Pages |
The Suzuki–Miyaura reaction has been performed using a phosphine-free perfluoro-tagged palladium catalyst that is readily immobilized on fluorous silica gel through fluorous–fluorous interactions (Pd-1/FSG). The reactions are carried out under aerobic and phosphine-free conditions with excellent to quantitative product yields, and very low palladium content (< 0.8 ppm) in the products was detected by ICP-AES. The catalyst can be recovered by simple filtration and reused several times without significant loss of activity.
Graphical abstractThe Suzuki–Miyaura reaction has been performed using a phosphine-free perfluoro-tagged nano-palladium catalyst that is readily immobilized on fluorous silica gel through fluorous–fluorous interactions. The immobilized fluorous nano-palladium catalyst can be recovered by simple filtration and reused several times without significant loss of activity.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A novel perfluoro-tagged nano-palladium catalyst (Pd-1/FSG) has been prepared. ► All reactions went smoothly in methanol/water and high yields were obtained. ► Very low palladium content (< 0.8 ppm) in the products was detected by ICP-AES. ► The catalyst can be reused several times without significant loss of activity.
