| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 51091 | Catalysis Communications | 2010 | 5 Pages |
Abstract
Porous palladium nanoparticles were prepared using a solution-phase approach. Their structures and shapes were analyzed by XRD, EDS, TEM and HRTEM. These palladium nanoparticles were used to catalyze the cycloisomerization reaction of N,N-diallylamide or N,N-diallylsulfonamide, and N-acyl-2,3-dihydropyrrole or N-sulfonyl-2,3-dihydropyrrole derivatives were therefore synthesized with very high regioselectivity and in good yields. The nano-palladium catalyst showed high efficiency and it can be reused several times. A hydropalladation mechanism was proposed for this reaction.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Lizhe Feng, Zhiyong Gan, Xiaopeng Nie, Peipei Sun, Jianchun Bao,