Article ID Journal Published Year Pages File Type
5134678 Journal of Analytical and Applied Pyrolysis 2017 10 Pages PDF
Abstract

•Pyrolysis behavior of polypropylene is presented.•Plain and Fe2O3-impregnated waste brick kiln dust are evaluated as catalysts.•Characterization of the derived liquid oils is discussed.•Fuel properties in comparison with petro-fuels are discussed.

The present study portrays the catalytic pyrolysis of polypropylene over plain and Fe2O3-impregnated waste brick kiln dust (WBKD) into liquid oils of fuel value in comparison with control (thermal) run. The catalysts were duly characterized by scanning electron microscopy (SEM), energy dispersive x-rays (EDX), surface area analysis (SAA) and x-ray diffractometry (XRD) and used in concertation range of 0.5-10%. The yields of the liquid oil as a function of catalyst concentration were studied and the oil obtained in optimum yield (96.70%) at catalyst to polymer ratio of 2.5% were submitted to atmospheric distillation in order to get gasoline (37-180 °C), diesel (180-250 °C) and residue (>250 °C) in comparison with the control/thermal run. The fuel properties of the gasoline and diesel range fractions determined according to ASTM methods showed good conformance with the petro-gasoline and diesel.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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