Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5139010 | Microchemical Journal | 2017 | 7 Pages |
Abstract
A method based on Matrix Solid Phase Dispersion (MSPD) for the determination of nine triazines in marine sediments was optimized in terms of dispersant agents, co-sorbents and elution solvents. Three dispersing agents: octadecylsilyl bonded silica (C18), graphitized carbon black (GCB) and diatomaceous earth, and four clean-up co-sorbents: Florisil, GCB, primary and secondary amine (PSA)/strong anion exchanger (SAX), and GCB/PSA were assayed. The best results were obtained with GCB as dispersing agent, without co-sorbent, using 20 mL of ethyl acetate as elution solvent. Finally the extract was concentrated to dryness, re-constituted with 1 mL methanol and determined by HPLC-DAD. The analytical recoveries obtained were close to 100% and repeatability and reproducibility were below than 3.5% for all compounds. The linearity of the calibration curves was excellent in matrix matched standards, and yielded the coefficients of determination â¥Â 0.9992 for all the target analytes. The LOQ values ranged from 0.022 to 0.037 mg kgâ 1. Finally the method was applied to analyse the target compounds in marine sediment samples from the estuary of A Coruña (Galicia, NW of Spain).
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Noelia RodrÃguez-González, MarÃa-José González-Castro, Elisa Beceiro-González, Soledad Muniategui-Lorenzo,