Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5141651 | TrAC Trends in Analytical Chemistry | 2016 | 41 Pages |
Abstract
NMR spectroscopy with compact instruments opens new perspectives for the use of NMR. While the field strength of compact instruments is low, they potentially match today's high-field instruments in methodical diversity, although by default they are operated in non-expert mode with a mouse click. Because size and price are low, they open new opportunities for the use of NMR spectroscopy. One is product and quality control and another is real-time reaction monitoring in the academic and industrial research laboratory on the workbench by observing nuclei such as 1H, 13C, 31P, 19F, 7Li and 11B. With compact NMR spectrometers, not only standard one-dimensional experiments can be executed to retrieve chemical information but also the two-dimensional experiments such as HSQC, HMBC, HETCOR and COSY. The state of the art and progress in compact NMR spectroscopy is reviewed concerning 1D and 2D spectroscopy along with their use in product control and reaction monitoring.
Keywords
FEPppmGPCMTBEHSQCNIRSBRSECHMQCCDCl3HETCORLOQPTFEUV-VisDEPTCompact NMRnuclear magnetic resonance2D NMRS/Nethylene oxidefluorinated ethylene propyleneUltraviolet-visibleSize-exclusion chromatographyPropylene oxideNMRFIDtwo-dimensionalNMR spectroscopyFT-IRcorrelation spectroscopyfree induction decayFourier-transform infraredparts per millionStyrene-butadiene rubberNatural rubberInfraredNear infraredFAME یا fatty acid methyl esters fatty acid methyl estersmethyl tert-Butyl etherlimit of quantificationSignal-to-noise ratioReaction monitoringHMBC یا Heteronuclear Multiple Bond CorrelationPMMApolymethylmethacrylatepolytetrafluoroethylenePolystyreneCOSYhigh-performance liquid chromatographyHPLCgel-permeation chromatographyDeuterated chloroformone-dimensional
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Kawarpal Singh, Bernhard Blümich,