Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5141902 | Vibrational Spectroscopy | 2017 | 28 Pages |
Abstract
Four new [60]fulleropyrrolidines were synthesized by cycloaddition reaction. The characterization of these [60]fullerene adducts by vibrational spectroscopy showed some unexpected and straightforward evidences of their molecular structure. In fact, the analysis of spectral regions around 527Â cmâ1 in the infrared and 269Â cmâ1 in the Raman spectrum has shown the existence of a correlation between the typical vibrational modes of fullerene moiety and the substitution of fullerene itself, highlighting that these spectral features can be used to elucidate the structure of the adducts. DFT calculations were also employed to compute vibrational frequencies.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Riccardo Barbieri, Luigi Abbondanza, Luisa Fiocca, Mario Salvalaggio,