| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5142191 | Arabian Journal of Chemistry | 2016 | 5 Pages |
Abstract
This paper describes the effect of thiophenol concentration on photochemical rearrangement of 2-phenylthio-3-aminocyclohexanols to the corresponding protected aminoaldehydes. The obtained aminoaldehyde is in equilibrium with its corresponding deoxyazasugar. The latter could be converted to the corresponding dehydropiperidine with a good yield in the same reaction media by controlling the thiophenol concentration. Also a proposed mechanism for this one pot transformation is reported.
Related Topics
Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Firouzeh Nemati, Ali Amoozadeh,