Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5142337 | Arabian Journal of Chemistry | 2017 | 9 Pages |
Abstract
Reaction of 2,2-dimethyl-1,3-dioxane-4,6-dione (Meldrum's acid) with various aldehydes in the presence of cyanogen bromide and triethylamine leads to the selective and efficient formation of full-substituted cyclopropanes at room temperature. The products were obtained in good to excellent yields. Structure elucidation is carried out by 1H, 13C NMR, FT-IR spectroscopy and mass analysis techniques. A possible mechanism for the formation is discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Nader Noroozi Pesyan, Ali Gharib, Mohammad Behroozi, Alireza Shokr,