Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5144593 | Ultrasonics Sonochemistry | 2017 | 19 Pages |
Abstract
A new mercury(II) coordination polymer, [Hg(4-bpmo)I2]n (1), (4-bpmo = N,Nâ²-bis(pyridin-4-ylmethyl)oxalamide), was synthesized, by branched tube method, and structurally characterized by single-crystal X-ray diffraction. Compound 1 is a polymer with a distorted tetrahedral HgN2I2 coordination environment. The thermal stability of 1 was studied by thermal gravimetric (TG) and differential thermal (DTA) analyses. Also 1 was prepared by a sonochemical process at ambient temperature. Reaction time and concentration of initial reagents effects on the size and morphology were studied. Nanoparticles of 1, was synthesized easily by a mechanical method (neat grinding). The resulting structures were characterized by scanning electron microscopy (SEM), IR spectroscopy and X-ray powder diffraction (XRD).
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Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Fahime Bigdeli, Hassan Hosseini-Monfared, Ali Morsali, Peter Mayer,