Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5144913 | Ultrasonics Sonochemistry | 2017 | 39 Pages |
Abstract
Nanoparticles of two zinc(II) coordination polymers (CPs), [Zn(μ-4,4â²-bipy)Cl2]n (1) and [Zn(μ-4,4â²-bipy)Br2]n (2) L = bpy = 4,4â²-bipyridine ligand, have been synthesized by use of a sonochemical process and characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR) spectroscopy and elemental analyses. The single crystal X-ray data of compounds 1 and 2 imply that the Zn+2 ions are four coordinated. Topological analysis shows that 1D coordination networks of 1 and 2 can be classified as underlying nets of topological types 2C1. Nanoparticles of zinc(II) oxide have been prepared by calcination of two different zinc (II) CPs at 450 °C that were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and IR spectroscopy.
Related Topics
Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Mohammad Jaafar Soltanian Fard, Payam Hayati, Azita Firoozadeh, Jan Janczak,