Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5150975 | Coordination Chemistry Reviews | 2016 | 20 Pages |
Abstract
Lanthanide(III) porphyrins are of typical SAT complexes, the photophysical and-chemical features of which can be tuned by the size of the metal center. Anionic, early lanthanide(III) mono- and bisporphyrin complexes exhibit very similar photoinduced properties as a consequence of a special type of aggregation, through the peripheral substituents. The rather slow formation of complexes and transformation between the mono- and bisporphyrins can be accelerated by the irradiation of the system. These by-processes play considerable roles beside the photoredox degradation and demetalation. Depending on the wavelength of irradiation, two types of photoproducts can appear: during the photolysis at the Soret-band, a radical type intermediate can be observed, which disappears in dark. However, irradiation at the Q-bands, generates the formation of a new, stable photoproduct.
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Authors
Ottó Horváth, Zsolt Valicsek, Melinda A. Fodor, Máté M. Major, Muhammad Imran, Günter Grampp, Alexander Wankmüller,