| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5151600 | Inorganica Chimica Acta | 2017 | 9 Pages |
Abstract
Oxalate serves as a template in the formation of di-zinc Schiff-base macrocycles linked by p- or m-xylylenes. NMR spectroscopy and X-ray crystallography both demonstrate symmetric structures containing μ2-κ2,κ2 oxalate. Treatment of one of the compounds with CaBr2 transforms bridging oxalate into the asymmetric μ2-κ1,κ2 form. The use of HCl enables oxalate removal as observed by ESI-MS.75
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jeffrey W. Beattie, Daniel J. SantaLucia, David S. White, Stanislav Groysman,