Article ID Journal Published Year Pages File Type
5151803 Inorganica Chimica Acta 2017 40 Pages PDF
Abstract
Six Ru(II) P-N donor complexes, both homoleptic and heteroleptic, were synthesized, using a novel disassembly process, from diruthenium(II,III) tetracaacetate. The complexes were fully characterized and the degree of P-N donor substitution was found to be sterically dictated. Electrochemical studies show higher redox potentials for those complexes with a greater degree of ligand π-acidity. One of the complexes displayed marked hemilability.110
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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