| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5151804 | Inorganica Chimica Acta | 2017 | 20 Pages |
Abstract
The trinuclear ruthenium-oxo cluster [Ru3(II,III,III)O(CH3CO2)6(H2O)3]·2H2O was prepared and its crystal structure was determined using single-crystal X-ray diffraction data. The complex exhibits the trapped-valence state delocalization between ruthenium centers at room temperature. The catalytic activity of the complex in hydration of nitriles and isomerization of allylic alcohols reactions is also reported.89
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Mixed-valence μ3-oxo-centered triruthenium cluster [Ru3(II,III,III)(μ3-O)(μ-CH3CO2)6(H2O)3]·2H2O: Synthesis, structural characterization, valence-state delocalization and catalytic behavior](/preview/png/5151804.png "First Page Preview: Mixed-valence μ3-oxo-centered triruthenium cluster [Ru3(II,III,III)(μ3-O)(μ-CH3CO2)6(H2O)3]·2H2O: Synthesis, structural characterization, valence-state delocalization and catalytic behavior")
Authors
Alla Dikhtiarenko, Sergei Khainakov, José R. GarcÃa, José Gimeno,