| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5151820 | Inorganica Chimica Acta | 2017 | 20 Pages |
Abstract
The dynamic behavior of three bisbipyridylruthenium(II)-nicotinamide complexes was demonstrated by temperature-dependent 1H NMR spectroscopy which revealed hindered rotation of nicotinamide in the XÂ =Â chlorido and XÂ =Â iodido complexes at ambient temperature. In contrast free rotation of nicotinamide on the NMR timescale was observed for the bisnicotinamide (XÂ =Â nicotamide) complex at 298Â K. DFT calculations suggested that hindered rotation is associated with intramolecular H-bonding which is strongest for the chlorido complex.147
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Nichola A. Smith, Pingyu Zhang, Luca Salassa, Abraha Habtemariam, Peter J. Sadler,