Article ID Journal Published Year Pages File Type
5151880 Inorganica Chimica Acta 2016 7 Pages PDF
Abstract
A neutral mercury(II) complex of composition [Hg(L)2]n (1), [L = N1-(3-hydroxypropyl)-5-fluorouracilate] is described. The Hg(II) is bound to the N(3) atoms of the two ligands and to the ancillary O(4) atoms of the uracil rings. The two bases are almost coplanar. Surprisingly, two hydroxyl groups from different units are also bound in apical positions. Unprecedented antiparallel CO⋯C-F interactions are described since they have a strong influence in the crystal packing of the complex.65
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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