Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5151880 | Inorganica Chimica Acta | 2016 | 7 Pages |
Abstract
A neutral mercury(II) complex of composition [Hg(L)2]n (1), [L = N1-(3-hydroxypropyl)-5-fluorouracilate] is described. The Hg(II) is bound to the N(3) atoms of the two ligands and to the ancillary O(4) atoms of the uracil rings. The two bases are almost coplanar. Surprisingly, two hydroxyl groups from different units are also bound in apical positions. Unprecedented antiparallel COâ¯C-F interactions are described since they have a strong influence in the crystal packing of the complex.65
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Antonio Bauzá, Angel Terrón, Miquel Barceló-Oliver, Angel GarcÃa-Raso, Antonio Frontera,