| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5151945 | Inorganica Chimica Acta | 2017 | 33 Pages |
Abstract
Two new thiopurine-κS-complexes, [RuCp(8MTT-κS)(mPTA)(PPh3)]+ (1) and [RuCp(8MTT-κS)(mPTA)2]2+ (2) were synthesized and characterized by single crystal X-ray diffraction. The thiopurine coordination was evaluated by DFT theoretical methods by study of the isomer complexes in gas phase and water.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis, characterization, X-ray structural determination and theoretical study of the complexes [RuCp(8MTT-κS)LLâ²] (8MTT = 8-methylthio-theophyllinate; L,Lâ²Â = PTA, mPTA; L = mPTA, Lâ²Â = PPh3; PTA = 1,3,5-triaza-7-phosphaadamantane, mPTA](/preview/png/5151945.png "First Page Preview: Synthesis, characterization, X-ray structural determination and theoretical study of the complexes [RuCp(8MTT-κS)LLâ²] (8MTT = 8-methylthio-theophyllinate; L,Lâ²Â = PTA, mPTA; L = mPTA, Lâ²Â = PPh3; PTA = 1,3,5-triaza-7-phosphaadamantane, mPTA")
Authors
Lazhar Hajji, Vicente Jara-Pérez, Cristobal Saraiba-Bello, Gaspar Segovia-Torrente, Manuel Serrano-Ruiz, Antonio Romerosa,