Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5152605 | Journal of Inorganic Biochemistry | 2017 | 12 Pages |
Abstract
A tri-nuclear Cu(II) complex containing a central, negatively charged 1,4,5,8,9,12-hexaazatriphenylene-hexacarboxylate core photocleaves plasmid DNA in 98% to 99% yield at low micromolar concentrations of complex (350 nm, 22 °C, pH 7.0). The cleavage process involves the generation of Cu(I) and hydroxyl radicals.115
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dominique E. Williams, Christina M. Fischer, Miki Kassai, Lourdes Gude, MarÃa-José Fernández, Antonio Lorente, Kathryn B. Grant,