Article ID Journal Published Year Pages File Type
5152783 Journal of Organometallic Chemistry 2017 6 Pages PDF
Abstract
Treatment of a germylene complex having a (H)W=Ge(H) moiety with 1 equiv of NHC gave a germylyne complex having a W≡Ge bond through stepwise proton and hydride transfer to NHC giving H2-NHC. Two kinds of intermediate complexes corresponding to (H)W=Ge(H)(NHC+) (zwitterionic) and W-=Ge(H) (anionic) systems were isolated and fully characterized.184
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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