| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5152871 | Journal of Organometallic Chemistry | 2017 | 17 Pages |
Abstract
A series of pincer-Pd-OH complexes containing strongly-bound cis-donor ligands is shown by DFT to undergo hydrogenolysis via an internal electrophilic substitution pathway. Use of hemilabile cis-ligands does not lead to hydrogenolysis of the Pd-OH bond, but rather hydrogenation to produce a water-bound Pd-H, matching the experimental results.87
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Marie V. Parkes, Wilson D. Bailey, Karen I. Goldberg, Richard A. Kemp,