Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5152987 | Journal of Organometallic Chemistry | 2017 | 16 Pages |
Abstract
synopsis: The molecular structures of the transition metal cyclohexasilyl complexes M(CO)5Si6Me11 * 0.5 n-C5H12 (MÂ =Â Mn, Re) were determined. Their silicon-silicon bond lengths are compared with those of other cyclohexasilyl compounds with respect to silicon-silicon bond activation. Cyclohexasilyl complexes are proposed as model compounds for metal-silicon interaction.178
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Florian Hoffmann, Jörg Wagler, Uwe Böhme, Gerhard Roewer,