| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5153094 | Journal of Organometallic Chemistry | 2017 | 14 Pages |
Abstract
We describe a simple and efficient ruthenium-catalyzed reaction in which propargylic alcohol HCαCβ-Cγ(R1R2)OH is split into carbon monoxide CαO, formaldehyde H2CβO and ketone (R1R2)CγO via cleavage of carbon-carbon triple and single bonds. A plausible reaction mechanism is proposed on the basis of ruthenium vinyl and formyl intermediates.125
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yih-Hsing Lo, Ming-Che Li, Li-Yu Huang, Guan-Jie Hung,