Article ID Journal Published Year Pages File Type
5153120 Journal of Organometallic Chemistry 2017 11 Pages PDF
Abstract
Reaction of three selected diphos ligands, viz. 1,2-bis(diphenylphosphino)ethane (L1), 1,3-bis(diphenylphosphino)propane (L2) and 1,4-bis(diphenylphosphino)butane (L3), with [{Ru(CO)2Cl2}n] affords di-ruthenium complexes of type [Ru2(L)3(CO)2Cl4], (1-3), which are found to efficiently catalyze hydrogenation of alkynes to the corresponding alkenes.150
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
Di-ruthenium complexes having diphosphines and carbonyls: Formation, structure, and catalytic hydrogenation of alkynes
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