Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5153154 | Journal of Organometallic Chemistry | 2016 | 31 Pages |
Abstract
For the first time, (1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-yl diphenylphosphinite chloride) (chloro ɳ4-1,5-cyclooctadiene rhodium(I))] and (1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-yl diphenylphosphinite chloride) (dichloro ɳ5-pentamethylcyclopentadienyl iridium(III))] complexes have been synthesized with high yields. The novel catalysts were applied to transfer hydrogenation of various using 2-propanol as a hydrogen source. Notably, rhodium(I) complex is much more active in the transfer hydrogenation, giving the corresponding alcohols up to 99% conversions in 5 min (TOF â¤Â 1176 hâ1).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Duygu Elma KarakaÅ, Feyyaz Durap, Akın Baysal, Yusuf Selim Ocak, Khadichakhan Rafikova, Eda ÃavuÅ Kaya, Alexey Zazybin, Hamdi Temel, Cezmi Kayan, Nermin Meriç, Murat Aydemir,