| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5153216 | Journal of Organometallic Chemistry | 2017 | 10 Pages |
Abstract
Formation of hexacoordinate (tBuPCP)IrH(Cl)(L) occurs via preferential coordination of L = RCN, pyridines trans to the hydride ligand causing the IrCl bond elongation. In the original (tBuPCP)IrH(Cl) and its (tBuPCP)IrH(Cl)(L) derivatives, chloride ligand is able to serve as a proton accepting site forming Clâ¯HX hydrogen bonds.452
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ekaterina M. Titova, Elena S. Osipova, Ekaterina S. Gulyaeva, Vladimir N. Torocheshnikov, Aleksandr A. Pavlov, Gleb A. Silantyev, Oleg A. Filippov, Elena S. Shubina, Natalia V. Belkova,