| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5153226 | Journal of Organometallic Chemistry | 2017 | 38 Pages |
Abstract
A ruthenium carbonyl complex, [Ru(CO)2(L)(Cl)2] (1) of a redox non-innocent thioether-containing azo-phenol ligand has been synthesized and characterized. Cyclic voltammogram of 1 exhibits Ru(II)/Ru(III) quasireversible oxidation (E1/2Â =Â 1.22Â V) along with ligand based reductions. DFT calculations have been used to interpret the electronic structure of the complex. Catalytic activities towards oxidation of alcohols have been studied.181
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Puspendu Roy, Apurba Sau Mondal, Ajoy Kumar Pramanik, Tapan Kumar Mondal,