| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5153255 | Journal of Organometallic Chemistry | 2016 | 10 Pages |
Abstract
A new polycyclic N-heterocyclic carbene featuring a fused 2,1,3-benzothiadiazol moiety was generated and characterized by 1H and 13C NMR spectroscopy. Complexes of type [MCl(COD)] and [MCl(CO)2] (MÂ =Â Rh and Ir) incorporating this carbene were prepared and characterized using spectroscopic and crystallographic methods. These new metal complexes show catalytic activity in hydrosilylation of acetophenone derivatives.
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Authors
Daniela Tapu, Ossie J. Buckner, Chance M. Boudreaux, Bradley Norvell, Monica Vasiliu, David A. Dixon, Colin D. McMillen,