| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5153384 | Journal of Solid State Chemistry | 2017 | 6 Pages |
Abstract
The fresnoite structure related novel reduced barium titanium chlorosilicate, Ba3Ti2Si4O14Cl0.91O0.09, were synthesized via flux method. An in situ reduction of Ti(IV) to Ti(III) achieved using Mg metal. The 3D structure consists 2D layers of fused Ti2O9 and Si4O12 and 2D layers of fused Ti2O9Cl2 and Si2O7 connected via barium atoms. Compound shows simple paramagnetism above 100Â K.456
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dileka Abeysinghe, Mark D. Smith, Hans-Conrad zur Loye,