Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5153418 | Journal of Solid State Chemistry | 2017 | 29 Pages |
Abstract
Eight new Zn(II)-based coordination polymers constructed from a flexible V-shaped long bicarboxylic acid and different N-donor ligands have been hydrothermally synthesized through fixing the metal salts and the solvent systems. The photoluminescent properties of complexes 1â8 in solid state were studied. Interestingly, 3 exhibits highly efficient luminescent sensing for Cu2+ cations and CrO42- anions, as well as detection ability for the different organic solvents and nitro explosives, in which indicates it could be utilized as a multi-responsive luminescent sensor. Furthermore, compound 3 also shows good chemical resistance to both acidity and alkalinity solutions with pH ranging from 2 to 13. Thus, multiphotofunctionality and fluorescent response to pH have been combined in the 3, which is the first example in the Zn-based hybrid materials.353
Related Topics
Physical Sciences and Engineering
Chemistry
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Authors
Jun Wang, Chao Bai, Huai-Ming Hu, Fei Yuan, Gang-Lin Xue,