Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5153435 | Journal of Solid State Chemistry | 2017 | 27 Pages |
Abstract
The dehydration process of the rhabdophane SmPO4.0.667H2O was studied over combination of in situ high resolution synchrotron powder diffraction and TGA techniques, a first dehydration was identified around 80 °C leading to the formation of SmPO4.0.5H2O (Monoclinic, C2). Then above 220 °C, the anhydrous form of the rhabdophane SmPO4 was stabilized and crystallizes in the hexagonal P3121 space group.217
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Adel Mesbah, Nicolas Clavier, Erik Elkaim, Stéphanie Szenknect, Nicolas Dacheux,