Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5153639 | Journal of Solid State Chemistry | 2017 | 18 Pages |
Abstract
The chemical reaction thermodynamics of SiC nanowires synthesized by carbothermal reduction reactions was investigated, and a novel two-stage growth mechanism was proposed. The growth mechanism involved the formation of initial SiC embryos by heterogeneous nucleation and the growth of SiC nanowires by a gas-phase reaction. The process involved the fast formation of gaseous SiO and CO crucial intermediates, and the further carbon reduction of SiO to SiC.309
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jianjun Chen, Lijuan Ding, Lipeng Xin, Fan Zeng, Jun Chen,