Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
51596 | Catalysis Communications | 2011 | 5 Pages |
The flower-like Ag/AgCl/BiOCl composite was prepared by a one-step chemical bath method at low temperature for the first time. The morphology, crystallinity, composition, and optical property were well characterized by scanning electron microscope, X-ray diffraction, energy dispersive X-ray analysis, UV–vis diffuse reflectance spectrophotometer and nitrogen adsorption-desorption. The Ag/AgCl/BiOCl composite displayed enhanced visible-light photocatalytic activity against rhodamine B, which was much higher than Ag/AgCl or BiOCl. The mechanism for the degradation of rhodamine B over the Ag/AgCl/BiOCl was discussed. The superoxide radical and chlorine radical or the hole played critical roles instead of hydroxyl radicals.
Graphical abstractThe flower-like Ag/AgCl/BiOCl composite was prepared by a one-step chemical bath method and displayed enhanced visible light photocatalytic activity against rhodamine B. The photo-induced holes, •Cl and superoxide radicals played critical roles in the photodegradation.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The successful fabrication of the flower-like Ag/AgCl/BiOCl composites.► The Ag/AgCl/BiOCl exhibits an enhanced visible light photocatalytic activity. ► The hole, •Cl and superoxide radical play a critical role in the photodegradation.