Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
51666 | Catalysis Communications | 2010 | 4 Pages |
Abstract
Dehydrosulfurization of 3-mercaptopropionic acid has been investigated in a fixed bed reactor using a silicalite catalyst in order to recover the hydrocarbon core. Under reductive conditions, acrylic acid was formed in high yield at 350 °C and atmospheric pressure as the desired product along the toxic H2S, whereas, carrying out the reaction in the presence of air, safer dihydrogenpolysulfides resulted as the co-product.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Cristina Della Pina, Ermelinda Falletta, Michele Rossi,