Article ID Journal Published Year Pages File Type
5179618 Polymer 2015 17 Pages PDF
Abstract
The phosphate ester capped polylactide was synthesized through employing calcium complex to catalyze the hydrophosphonylation reaction to generate alcoholic chain-transfer agent and immortal ring-opening polymerization in situ. The Tonset of the afforded PLLA was 338.22 °C, 57 °C higher than that of PLLA ended with benzyloxy group. This intensification and integration process is one hundred percent atom-economic efficiency.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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