Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5179618 | Polymer | 2015 | 17 Pages |
Abstract
The phosphate ester capped polylactide was synthesized through employing calcium complex to catalyze the hydrophosphonylation reaction to generate alcoholic chain-transfer agent and immortal ring-opening polymerization in situ. The Tonset of the afforded PLLA was 338.22 °C, 57 °C higher than that of PLLA ended with benzyloxy group. This intensification and integration process is one hundred percent atom-economic efficiency.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Na Liu, Changguang Yao, Fei Lin, Bo Liu, Dongmei Cui,