Article ID Journal Published Year Pages File Type
5180116 Polymer 2015 34 Pages PDF
Abstract
Supplemental activator and reducing agent atom transfer radical polymerization (SARA ATRP) and electrochemically mediated atom transfer radical polymerization (eATRP) of N-isopropylacrylamide were well controlled with relatively low concentration of CuIIBr2/Me6TREN complex (500 ppm), at high water content (84 wt% in H2O) and at low temperature of 0 °C. Diblock copolymers with molecular weights close to theoretical values and with narrow molecular weight distribution were prepared.205
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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