Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5183107 | Polymer | 2012 | 6 Pages |
Abstract
Here, we present a novel constitutional dynamic chemistry controlled reaction induced crystallization strategy for the morphological controlling of aromatic polyazomethines. Complex nanostructured polyazomethines with sphere, elliptic, discus and disk-like morphologies can be readily fine tuned by varying the ratio of reagents in the dynamic imine exchange reaction. After pyrolysis, hierarchically nanostructured carbons can be obtained. The study revealed the concert of constitutional dynamic chemistry and reaction induced crystallization could provide a powerful strategy for the complex morphological control of aromatic polymers.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yuzhi Yan, Lu Chen, Hongjun Dai, Zihua Chen, Xiang Li, Xikui Liu,